Cover Picture: Visible‐Light‐Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane‐Oxindole‐Pharmaceutical Hybrids (Angew. Chem. Int. Ed. 31/2023)

Carbon-centered carboranyl radicals are an underdeveloped compound class. In their Research Article (e202305088), Zhi-Xiang Wang, Xiang-Yu Chen and co-workers show that the combination of carborane phosphonium salts KOAc forms a photoactive charge transfer complex for generation carbon-centered radicals, allowing access to various carborane-oxindole pharmaceuticals. Photocatalysts Photocatalysis Single-Cell Analysis Enantioselective Synthesis